Title:
Synthesis and Characterization of Imidophosphorane Ligand Derivatives For Crystalline, Low Coordinate F-Element Complexes
Synthesis and Characterization of Imidophosphorane Ligand Derivatives For Crystalline, Low Coordinate F-Element Complexes
Author(s)
Tateyama, Haruko
Advisor(s)
La Pierre, Henry S.
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Abstract
This thesis describes the development of imidophosphorane ligand derivatives in order to access low coordinate, crystalline complexes of lanthanides and actinides. Chapter 1 provides a general overview of the low-coordinate f-block complexes and ligands used in achieving such systems. Chapter 2 describes the synthesis of four imidophosphorane ligand derivatives, including synthetic challenges encountered. These ligand derivatives were developed to address synthetic challenges of limited solubility and crystallinity from the ligand developed in the group. The availability of these four ligand derivatives will give us a toolbox of ligands in addressing such synthetic challenges, eventually with the goal of accessing low-coordinate, crystalline f-element complexes. Chapter 3 showcases the crystallographic analyses of the four imidophosphorane derivatives.
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Date Issued
2022-08-03
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Text
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Thesis