Title:
Structural manipulation of conjugated polymers
Structural manipulation of conjugated polymers
Authors
Bakbak, Selma
Authors
Advisors
Bunz, Uwe H. F.
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Abstract
The syntheses of new classes of conjugated polymers are presented. The synthesis of novel alkyne bridged trispyrazolylmethane ligands, their coordination behavior and their crystallographic properties are studied. A series of functionalized poly(paraphenyleneethynylene)s, PPEs, are produced by click chemistry with post and pre-polymerization. Unpredictable solid-state polymerizations of defect free conjugated polythiophenes are investigated. Finally, by click chemistry aromatic diazides and aromatic diynes are coupled to produce a library of 1,2,3-triazoles and new conjugated polymers, poly(arylenetriazoline)s.
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Date Issued
2006-01-13
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7684655 bytes
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Text
Resource Subtype
Dissertation