You know all that mess right now. But yes you're right. We love this story. It was like OK thank you. So I work in the era of combustion so combustion you know and it very simply is burning stuff. OK. And. Specific And what I want to talk about today is assuming you have a power generation cycle that you want to limit the C O two generation from and it involves a combustor What is that what are the implications that has on the on the combustor about what how does that how does that impinge or crimp. Has the ability of the combustor to operate. You know basically what are the new challenges that that place is now. Many of you may not be familiar with the whole area of combustion you might realize that combustion is an area that you can study and get. Ph D. in fact I didn't I didn't know that until I came to graduate school that there was actually people working on combustion as a. You know a. Is a field of study. You know I've always like to make fire I'm sure many of you may share that primordial desire. I've I've made fires my whole life when I had a really neat job opportunity. Through college where I worked for the United States Forest Service in the Pacific Northwest in Alaska fighting fires. And to I always thought that was a summer job I never knew that would turn into a career of making fire and studying it but so I know it's a fun job and it's very interesting. And I thought it would give you a little bit of perspective on combustion research and the main thing is that you know combustion as a as a methodology for energy conversion is ubiquitous. You know if you think about transportation you know you're your car a truck. You know by and large these devices use internal combustion engines whether it's a diesel or or a gasoline engine. Which which ultimately relies on the burning of of some fuel to release heat and even if we start looking at a electrified transportation sector. Alternately the source of energy is going to come from power. So you know and also if we look at power generation. The majority of power generation the United States in the significant majority of power generation in the world comes from the combustion of natural gas or some sort of oil or some coal. You know and then if we look at energy intensive industrial processes sort of the the backbone of U.S. manufacturing and world manufacturing you know starting with very energy intensive of processes like glass making aluminum making steel making you know combustion is very important and also just a whole host of other of other things. And then finally. Just moving into domestic applications. If you have a water heater in your home. It's more than likely. Relies on a flame fueled by natural gas or a heater which will be turning on this winter. Many of those rely on combustion or even instant water heaters which you might have in the kitchen. Those oftentimes are lying combustion. And so advanced combustion remains a very very vibrant research area. For because primarily because of the it's primarily regulatory driven the need to continue generating low low cost reliable power energy. But yet with substantially reduced emissions of particulates or so or nitric oxide which make acid rain or carbon dioxide or even what we're going to talk about today which is carbon dioxide. So. Just a that was just a little context on combustion in general through this lighting here many of you may not know that Georgia Tech has a major combustion activity we actually have the largest university group in the country doing combustion for transportation and power generation there's about eighty people in all working on this. Where we focus on clean energy for power generation and propulsion. OK All right let's. That's a background let's start by talking about. What's the role of the combustor within the larger energy system. Let's just let's think about a gas turbine. The reason I want to focus on gas turbines here is that if you look in the United States almost all new power generation capacity over the last ten to fifteen years has been natural gas fired combined cycle power plants. So if we look at a gas turbine that uses a brain cycle. That's a steady flowing brain cycle. And this is an equation. For the thermal efficiency efficiency with which the heat energy. When the fuel is converted into useful work or or power. And it's basically a function of the compressor pressure ratio and gamma which is the ratio of specific heats and. What you can see here is that you might it might not be immediately obvious where the combustor fits into this this very important parameter of the overall cycle efficiency. And that's because it doesn't. The combustor has little effect on these very macro parameters like cycle efficiency how much it costs to generate or how much fuel it takes to generate. Overall. Kilowatts rather this is largely driven by the cycle the larger cycle the combustor is basically a black box within this larger cycle you know whether you're talking on a simple cycle power plant or a combined cycle power plant depends on the pressure overall pressure ratio of the device with the firing temperature of the devices and so forth. So you might ask yourself OK So why is where where does combustion become important. So this slide basically outlines the key performance metrics which this energy system would require of the combustor you know sort of a I guess the key ground level requirement is that whatever you're the combust has got to be able to burn your fuel if your fuel doesn't burn nothing works. And so really the key metrics which are combustor has to satisfy is I would group into four categories operability just the ability to operate the system. Emissions fuel flexibility in turn down so we can just tick through these and just walk through these operability for example important to blow out a these devices in order for them to be have a have a small footprint but still generate a lot of power have had a very very significant power densities and so the flow velocities through a modern energy device might be. Eighty meters per second or two hundred fifty feet per second. Now imagine going out in a hurricane and trying to hold a match and not having the flame just blow off so it's a very significant challenge in particular. Lee as we. Look toward low C O two cycles or low knock cycles these devices are oftentimes operating right on the edge of where the flame wants to wants to exist so blowouts a big concern. In order to push lies this a little bit just think about the next time you're on an airplane. Everything I said about a combustor on the previous slide would apply to the combustor inside an aircraft engine. You know the ability of. You know if you want to figure out how far an airplane can go on a given tank of gasoline. You know the combustor doesn't enter the calculation. Until the combustor blows at thirty thousand feet and have no flame then it really becomes a personal interest to you. Especially if the pilot can't rewrite and this does happen by the way. You fly through a big rain cloud you know all that water gets ingested sometimes flames do blow out. And so this is a big operability issue. Another one would be combustion instability I'll talk about that a little bit. Turns out that these are these are vibrations in the combustion chamber it's one of the most significant issues encountered with with high power density combustion devices. So again. And what basically happens when you have these vibrations is that causes parts to break. And you get hot and if you think about of the combustor is the. In any gas turbine that is the most severe operational regime in the system it's the highest pressure highest temperature. So you know. Undue stress can cause things to crack and break in and go downstream and cost catastrophic destruction so overall der ability and reliability of everything downstream the combustor critically depends upon on that. Then you have then you have I will go into all these issues. Emissions is a key high level driver. I'll talk about that a little later feel flexibility is important. As natural gas prices have gotten increasingly volatile. Power Plant operators want to be able to be able to use the lowest cost fuel and so sometimes that's natural gas. Sometimes it might be fuel oil. If we look toward the future. This might be. A gas a FIDE bio fuel or a gasified coal feedstock and so the the that the fuel composition. The ability of the system to operate over a wide range of fuel compositions is really important and lastly turn down the ability of the system to not only operate at one power level but over a whole range of power levels so again if we think about the aircraft example you want the engine to work not only at full power but also at idle. And at half power because you need the whole thing. And as well as all talk about. As we start looking at some of these low C O two cycles it really has important implications in all of these and if you don't meet these requirements. Nothing nothing happens you know you're dead in the water. So what I would just I want to show you two case studies to show you how this stuff has been very very important over the last fifteen years. Not for C O two emissions but for Knox emissions. Since the passage of the Clean Air Act. The nitric oxide emissions and C O emissions have been regulated and this is caused a very significant paradigm change in the way that combustor does are designed and this is caused lots of problems and issues lots of problems and issues which are directly motivating a lot of the research that we do and in our lab and the same types of problems and issues will be even more exacerbated with some of the C O C O two cycles. So I talked about operability I'll give you a couple examples for LHO Knox technology. This right here is a bore scope of the turbine. So this is the rotating piece of equipment downstream of the combustor in a heavy frame gas turbine this is a multi hundred million dollar piece of equipment. And this is the most expensive piece of it. It's the part that has to take the high temperature gas and spin it. Tens of thousand R.P.M.'s per second and basically what happened here was this come this come. In this system it had an A. Combustion instability which caused a crack to grow in propagate a piece flew downstream it sheared off three blade and this is about a fifteen million dollars failure. And in fact if you look at across the whole fleet of installed power power base broken parts due to problems in the combustor it's the single largest fuel cost single largest cost. Besides fuel for gas turbines So this is pretty significant. In fact I just for fun I pulled I keep a file of this kind of stuff. Where that where these types of problems which are directly. Aligned with the type of research work that I do in my lab shows up in the popular press so this is actually this is from C.N.N. Money from two thousand and five. Calpine is a power producer in the West Coast. It went bankrupt about two years ago. It's now back out of bankruptcy. And so they were basically hurt very badly when natural gas prices went up went up quite a bit. Which which drove them into bankruptcy but I just highlighted a quote here and where it says Calpine corpus unexpected costs due to equipment failure in the fourth quarter were related almost entirely to turbines purchased from Siemens actually these were Westinghouse turbines Calpine executive said Thursday in a conference call with Wall Street analysts were if you're seen as you've got to love this. I love seeing this in C N N Money. And then we then you can see down here the company which has built its huge fleet of natural gas fired fired power plants the United States over the past several years said equipment failure across a forty five point three million dollars were a significant part of the downturn in response. So this is directly related to the fact that these systems were using state of the technology it was really deployed before it was ready to be. Here's another one this is from the London Financial Times this relates to a power plant in Chile. Title is daggers drawn over a new one now in CO was a power site in Chile and. Basically what happened was. The power plant decided to reject the plant which is which is an option in the contract where they basically told Siemens. Thanks for putting in this. Multi hundred million dollar plant but we don't want it it's yours. Give us back all our money. And the reason for that is they were eggs. Well they were exacerbated by repeated breakdowns at the new plant So for example one of the things that happened was these plants have very very large ceramic tiles in the combustion chamber and they had these these acoustic oscillations which I referred to which actually took one of these big tiles shook it loose it shut downstream it took out the whole turbine. So it brought this whole plant brand a beautiful brand new plant down and it. As you can read down here the trouble could not have come at a worse time for Coburn the mainly hydro electric generator and this came after a major drought years so the hydroelectric power was way down all the sudden lost their. Sort of the centerpiece which were they were going to be making up the power and in fact Chile had rolling blackouts for about a year cost about three hundred million dollars in economic. Lost revenues according to some estimates due to these combustion problems associated low knocks. So that's another one. Actually here's the last one you know this is from the Philippines were Siemens is actually seeking arbitration because a power plant that they were building. They're being sued for hundred million dollars again related to these very very significant problems. So it's like I said I just want it. These are basically case studies the kind of experience that we've gained over the last ten years. Related to knock the same kind of issues are going to be very very challenging with C O two. So I just want to give you that perspective. Let me give you so that that's an opera build a case study I'll give you one more time talk about operability we can also talk about turn down really really important that if you build a power plant you want to be able to very nimbly and research and responsibly respond to electricity demand part. If you need high power you ought to be able to operate with high power if the power to me is low or you want to be able to to not. This is a a graph showing normalized load for a very very large combined cycle power. Point as a function of time and what you can see is there basically turning it on in the morning and shutting it off at night turning it on in the morning. Shutting off at night. Now this is a huge plant lots of metal which means the whole thing is getting heated up in the morning shut down at night it was not designed for this this plant was designed to run for three years straight without shutting it down after three years to be shut down and taken apart. In fact this is the C.E.O. of Siemens one of the comments he made at a power conference was he said if. The one industry trend he would have never have predicted in the early ninety's was that the huge fully of natural gas fired power plants that they were deploying which were designed to operate and a base load capability to just run for years on end would be cycled the run turned on the morning turned off at night. Well why did they have to do this while they had to do this because they got whacked with with with with two two high level drivers one is natural at all. This could new capacity one online seemed like a great idea when natural gas was cheap natural gas prices went way up all this and it wasn't profitable to operate these devices except during peak power demands on the price of electricity was high during the evening. It wasn't profitable to operate these Well ideally what you'd like to do is turn the power down maybe to ten or twenty percent let the thing idle overnight and crank it back up. Well you couldn't do that because what would happen is that your C.E.O. emissions went through the roof they went out of they went out of compliance with the plans permit. So rather they had to shut this whole power plant down Bring back on. OK so I don't want to I don't want to beat this point to death but I guess the key point is there's a lot of tradeoffs and challenges which drive the larger energy system which come right back to the combustor particularly as we look at loan ox technologies almost all of the key the key challenges derive from operability issues with the combustor sea of lots of trade offs and challenges between. Turndown operability emissions and overall cost and complexity of the system. So with that. Is it sort of. A little bit of background now. Now we can focus on low C O two combustion again. The C O two emissions the same point they're set by the when you pick your fuel in your cycle the C O two emissions is fixed. You know a good or a bad combustor is going to you know a combustor is basically a C O two in a water generator a good or a bad combustion system organ is going to do the same thing really. It sets the combustion configuration and challenges and so the key combustion research areas then fall out of what does what are the requirements in a place in the combustion system and they're quite different depending upon whether you want to capture your carbon prior to the combustion process after the combustion process or if you want to burn and near zero net C O two emitting fuel like a like a biofuel So what I want to do is I'm going to tick through some of these in and talk through what's happening there. So we talk about pre-convention carbon capture the key idea here is you remove the carbon prior to combustion. And really what that means is you have to have a combustion system that's capable of burning a high hydrogen fuel for example I can I just integrated gasification combined cycle. So you could take a biofuel you could take coal you could take some liquid fuel you gasify it. Turns it into a synthesis gas hydrogen and C.E.O. then you run it through a water gas shift reactor to shift to shift it to basically hydrogen and C O two you pull the C O two off and you can be running a high hydrogen fuel through the combustion. Well hydrogen induces very significant combustion issues primarily because hydrogen is a very very different molecule than methane or some some heavy duty oil. Hydrogen has a very high flame speed. So if I were to fill this room up with with methane an era natural gas and I was delighted spark the flame would propagate out at some speed we call that the flame speed. If I was to do the same experiment with hydrogen it would be almost an well over an order of magnitude faster. That really is the crux of the problem. And so you get a problem called flashback where the flame doesn't want to sit in the combustor which is where it's supposed to be that's the part designed for. High temperatures it's got cooling flows rather plan was to shoot upstream This is actually a visualisation flow. The flow is going this way the flame doesn't want to sit down here where it's supposed to it's actually this is a time series showing the flames shooting upstream. Into the passages not designed for the Flames is that image taken in a lab. And so on the ground. What this does is if you are if you buy up a one of these systems today it will have a very specific warranty which will limit your hydrogen to on the order of less than five percent by my boy. You simply the technology does not exist today if you wanted to burn a sin. Gas in a low knocks combustion system. You can't buy the technology today to do that because because of this issue. So if you. But now that's not to say there aren't plants there are power plants out there burning hydrogen fuel so there's some of them burning ninety percent hydrogen. There are a number of of of boilers in Texas which are taking off gases from refineries which are very very high hydrogen. But they have to use older high basically high Knox technology which then takes additional scrubbers Yes sir. And yeah combined cycle power plants. Yeah I'm particularly talking about about gas turbines but you get similar challenges they show up in slightly different ways with. With I.C. engines you know particularly the type engines you get similar there are a parallel set of issues that arise there. So. This is just some data illustrate. The same point. This is some terminal flame speed data which was taken in our lab. This is that basically implying that the speed with which the terminal flame propagates as a function of the percentage of hydrogen and you just get massive increases in the flame speed with hydrogen. Another big issue is the same issue of combustion instabilities which I talked about earlier very very problematic with hydrogen. The designs that you have to that you have to do to make these systems capable of burning with hydrogen. As well as Linux makes them very very susceptible to large amplitude of coast acoustic pulsations this is actually a simulation taken made by one of my colleagues showing. The yellow is an instantaneous image of what the flame looks like in one of these systems the blue is vorticity So this is these are basically vortices and what's happening is you get acoustic waves which excite vortices which disturb the flame and you get these very very large sample to pulsations and and then this kind of stuff happens. This is called a transition piece that connects the combustor to the turbine and chunks break off and they go off and then they cause multi million dollar failures. This is just another image of a of what's happening during one of these instabilities this is what we call this planar laser induced fluorescents basically what we do is we take a laser we shine it through the flame in a very specific wavelength. Which makes radicals fluoresce and you get a nice. A nice shot of what a highly three dimensional. Contorted flame looks like if you were to take a cut through it. So what's happening is this fuel an heiress coming through here and this interface right here is the instantaneous location. Where over a fraction of a millimeter the fuel is being consumed internally products so flames are very the actual flame itself is extremely thin but the main thing what you can see is as you walk through this this image is you can see the flame is getting longer. For example here the whole flame looks like this you see this big vortex which is grabbing the flame contorting it. It's causing this instability. Which which is very problematic with hydrogen. OK Let me shift gears a little bit here. I've talked about the key challenge associated to combustion challenge associated pre-convention carbon capture now talk about post combustion carbon capture and. The challenge here arises from the fact that if you're going to have a sequester will stream primarily composed of as large a fraction as possible of C O two and water you can condense the water out. But you know you. You know preferably you'd like to have as you like to increase the C O two volume fraction. And there's two ways you can do that either you can have exhaust gas research elation we've basically re circulate the exhaust gas back around. Or you can do what's called Oxy combustion where you say forget it I'm not going to burn air. Rather what I want to do is I'm a have an air separation unit I'm going to take the oxygen. I'm going to burn oxygen fuel so I don't have any of the nitrogen that that that drives down the mole fraction of C O two in the exhaust. However you burn oxygen and fuel but it's a very very high temperature flame you'd never be able to deal with the material problems. So what you do is you control your flame temperature by diluting the oxygen with recycled steam or with recycled C O two. This is a picture of a power plant in a demonstrator a five megawatt power plant in California operated by a company called Clean Energy Systems and they have money from the U.S. Department of Energy and California Energy Commission to do this with recycled steam. So they're basically burning oxygen and methane and they're basically dumping steam into the system to keep the flame temperature down but then they basically generate an almost pure C O two exhaust ring from the system. Now this particular site they're not actually sequestering the C O two. But they did the same company clean energy systems did just receive a very large do a grant to build a larger plant where they will actually be sequestering it. So this is the kind. The kind of technology. I'm talking about. So you know if you think about. Well what's the key differentiator with from one of these systems from bring in air when air the oxygen and nitrogen nitrogen ratio is fixed and your key knob that used to control flame temperature story you're going to basically run with lots and lots of excess air. And you're. In terms of emissions Knox and C.E.O. are your major pollutant concerns if you look look at an oxy system. The way you do this is you adjust the carbon dioxide oxygen ratio to control flame temperature and you want to run this thing at a story gallantries absolutely close to one is possible. The reason for that is if you're running. You're now paying for the oxygen. You know it's not for free anymore. So if you don't want to run with lots and lots of excess oxygen like you do with the in air system. See you but you're also paying for the fuel so you want to every bit of oxygen fuel which you're paying for you want to be burning and actually running at a store counter one raises lots of interesting kinetic issues and then if you look at the emissions basically you're looking at basically zero knocks emissions unless you have nitrogen in your fuel. But you get very significant c O. levels and then you start worrying about things like oxygen emissions as well which we'll talk about and then it. So if you look at some of the challenges associated with the C O two issues operability pops right up big big concern. I should have showed you earlier this is an S R seventy one during a high G. turn this is a very graphic illustration of what blow off is the this this is not supposed to be here. It's supposed to be you know right about here and but what happens is all that C O two or Iraq or steam in the system it inhibits the chemistry. Those are supposed to be products if you think about your chemical reaction equations you have stuff going to products and if you take all those products and you put on the left hand side it. It it really throws off the equilibrium. Levels are basically wants to drive the chemistry the other way so flame loft is basically a big concern and so what that means is turn down. Remember turndowns important you want your system to be able to operate at whatever power leveled your operator would like it's reduced if you have less turned down relative to an air fuel system. I talked about emissions. With these type of emissions that I'll tell you that Kimberly a power plant. If you were to stick your nose in the exhaust you'd probably be dead in a fraction of a second because I can guarantee you the C.E.O. levels are probably on the order of percents not P.P.M. which we normally worry about you know you think will hundred ppm C O you get a headache in a thousand you start vomiting you know whatever the continuous This is per cents. Because what happens is this well in that case with all that steam they're basically killing the chemistry but you know if you have very very high. Theo to levels even from an equilibrium point of view you get an order of magnitude increase in exhaust C O O C O's a pollutant it's also a loss in combustion efficiency of think about it. That's see it covered up carbon oxides of fuel. It's got a lot of energy in it. And it's feel that you paid for it and then. Oxygen Well oxygen is normally a major exhaust effluent but again you're paying for it for one you don't want to waste it. You know one oxygen coming out the exhaust and that also if this is a major near term application of all the C O two would be for enhanced oil recovery take the C O two and you use it to get or oil which means have to put in a pipeline or pipelines have to have to have. Stringent specs on oxygen levels. So you could have a catalyst to pull the oxygen out post system or you preferably you'd like to design your combustion system such that you basically emitting very very low levels of oxygen and turns out that these two compete against each other. This is just an equilibrium calculation and if you look at you can also look at this from a kinetics point of view but you know if you were to plot the flame temperature on the X. axis versus a story on the Y. axis and. You can see we're operating you're going to want to run right near a store counter of one equipment ratio of one so you're balanced and the solid lines are lines of constant C L in parts per million. So when you're rich you got lots of C.E.O. you know twenty thousand parts per million. As opposed to one hundred parts per million. In the dash lines are oxygen. Levels also in parts per million. So here if you're you're leaning out lots of oxygen versus appear you don't have much. And the two are not going in the same direction that to balance C O in Oxygen's a pretty tight balancing act. And so what happens is if you put all the stuff together some really interesting interesting combustion challenges associated with the overall operational space if you think about this graph well low temperatures Bloss a big issue. This is the same temperature versus the economics of Bloss a big issue over here going as you start going richer. C.-O. becomes a big issue as you start going leaner oxygen becomes an issue and what you hope is that when you draw these lines in a real system. It's they're not mutually exclusive. There is actually an operational space and so there's lots of interesting combustion challenges which are working on Open Source of trying to model and characterize where these lines are as a function of pressure and temperature and fuel and then also developing strategies to try to open that box up so you actually have a system with some flexibility. OK so I talked about combustion challenges for pre-convention capture post-concussion cap which are. I think I've talked long enough so I'll just throw this up here. There's also some interesting things associate with combustion of biofuels. And it sort of depends upon whether you're looking at a gasified biofuel or a liquid biofuel So gasified bio fuel that's basically a synthesis gas. You know from a combustor point of view I don't care whether it's your it's coming from a tree or from coal. You know the hydrogen C O ratio changes a little bit the billions change but it's basically the same problem as I talked about earlier if you talk about. A liquid derived biofuel then you get some interesting things particularly you start looking at Bio oils. They have some really interesting this viscous properties. So you get some very complex atomization evaporation combustion characteristics they don't vaporize in the conventional manner of that we're used to thinking rather you get what you're called micro explosion. Atomization characteristics are the things don't just evaporated get smaller. Rather they as they as they heat up also and they fret they fracture and they fragment into thousands of small micro droplets. OK so just let me just wrap up just say there's lots of exciting challenges associated with putting all this stuff together feel flexibility. What I call Clean Air Act emissions which is knocks and then we throw in C O two that adds to it and then if you start adding the additional requirements of operational flexibility reliability and cost that that really it starts making. Lots of interesting problems for us to work on. OK Thank you all for your attention but thank you. Yeah. Really really. Yeah I'm not too worried. I did a lot of soul searching five years ago and I decided you know I think. The U.S. has got a whole lot of coal. We got out as of the last two years we got a lot of natural gas. I think that very those very pragmatic considerations are going to keep combustion business for the next hundred years. You know I've seen that some of the projections from from G.E. Energy Siemens energy or Exxon. And you're just there internal projections. You know even out to twenty one hundred. I mean for our lifetime and my children's lifetime it's. There's it's. You know I can't nobody can predict the future but there's very reasonable scenario suggesting that that these are probably going to have to be dealt with. In that way or if Andre wants to rebut that and I have. All my heart I very. Yeah that would be you know. I've never seen that were you I mean why would you. I know. Why I'm mad. Yeah they are in fact if you look you know the U.S. the Department of Energy but three years ago they awarded fifty million dollars to G.E. and Siemens to develop a high hydrogen turbine. So which. It which has involved them looking at totally new combustor design paradigms two that can be used inside of a pretty combustion carbon capture scheme to burn out high hydrogen it has to be a totally different combustion paradigm. Yes ma'am. And. Yeah so. Almost everything I said here carries directly over the airline the aircraft engine applications a couple big differences so if you start looking at these big efficiency increases that means you're talking about big increases in overall pressure ratio. So you know versus Well a power plant might be running at fifteen bar or state of the art system an H. class turbine might be right. Eighteen atmospheres these systems are running up and fifty atmospheres. And so. A couple big issues well if OK if you look at it if you look at like a G.E. the Major there is the three major companies General Electric Pratt Whitney and Rolls Royce slightly different philosophy G.E. has gone towards more of a pre-mixed combustion approach so a lot of these these challenges that I've been talking about have been have been driven by the fact that you are pre-mix in the fuel in the air so you have a combustor here rather than dumping fuel in the air in the combustion chamber and letting the mix and burn where you can't control the story key on the tree and get a very high temperature flow makes a lot of knocks you pre-mix the fuel in the air upstream. So you have this big volume of combustible mixture pre-mix but you can control the story. Q How much you can get a low flame temperature will G.E. has basically made their aircraft look kind of pre-mixed. Which has introduced a lot of these issues in fact I think quite relieved about Boeing's delays in the seven eight seven because they've had a lot of problems with the development there Gen X. engine because the exact same issues on time at Pratt Whitney what they've been they've developed what's called R Q L technology. Which is much more near term practical hasn't suffered from many issues but it's its ultimate ability to limit Clean Air Act type emissions or you know I K A regulated missions like Knox and C.E.O. is is much more limited. So but even practice starting to look toward more pre-mix technologies but in an aircraft type environment where you're running with a liquid fuel a big difference between a liquid fuel. And methane is what's called the auto ignition temperature if you take a mixture of deck. You know decking which is basically Jet A jet is basically decking you mix with fuel and you fill it. You put in a box you increase the temperature of the box at some temperature it goes bang. You know it burns. Well that's and then you do the same experiment for methane air. Well methane air. It's over and over about a thousand degrees for a decade it's about three hundred. Which means that that for an aircraft type application I will I will go to the picture. You are trying to pre-mixed but the stuff is wants to burn it wants to burn and so you have this you're trying to walk this tightrope where you have to give it enough time for it to mix so that you control knocks without a lot of igniting an auto ignition has been G.E.'s. Biggest issue with the Gen X. engine which is their seven eight seven engine. A lot of. Whole market. All. Yeah I do. OK I my knowledge in this is somewhat limited but my understanding is if that they're using World Bank financing and there are certain requirements of the plant has to meet on emissions and so for example this this plant that I showed you the very beginning in the Philippines where they had that lawsuit. The only reason they used the low Knox technology was so that they could get some World Bank funds to help build the plant. If they're not than I don't think they care at all about emissions and so a lot of the stuff comes off the table. That world. Well we'll. Yeah but there are you know I know India and China there's there's lots and lots of interest in in the same in these same type of technologies that I talked about here. And again that. I don't know if it was but I do know that they put in a whole bunch of women in Georgia. You know all the years. You know actually there is an interesting interesting comment there was there was an article in power engineering where a guy was talking about how can we how can we meet these what is the Waxman Markey. Some of the goals that they have for the U.S. C O two emissions which set some certain requirements I think by the year two thousand and twenty. And basically what the guy said is the best way that we can the best thing we can do to meet all those requirements is only build colp of coal fire power plants and he said a little bit tongue in cheek but his key point was. We've got so much nasty legacy stuff out there that's our problem if we could just take all the coal fired power generation the US and replace it with best available even not even a gas turbine but just a boiler would be there already. Which is an interesting comment. You know just if it's just deploying best available technology. In a in a cost competitive way is really powerful you know I'm certainly invested in developing new technology but you know there's a lot of good stuff out there just from a business point of view it's deployed. You know getting the cost down and that's.