Title:
Metal organic frameworks based microcantilever gas sensors for detection of volatile organic compounds
Metal organic frameworks based microcantilever gas sensors for detection of volatile organic compounds
Authors
Ellern, Ilya
Authors
Advisors
Hesketh, Peter J.
Advisors
Person
Associated Organizations
Organizational Unit
Organizational Unit
Series
Collections
Supplementary to
Permanent Link
Abstract
Metal Organic Frameworks (MOFs) are a new class of nanoporous materials with
high surface area, thermal/chemical stability and a taylorable pore size. These properties
make MOFs ideal for storage and gas separation applications. Piezoresistive
microcantilever sensors are microfabricated devices that are highly sensitive to surface
strain due to doped single crystal silicon regions. Changes in resistance generated by
surface strain can be measured with a high degree of accuracy using a Wheatstone bridge
and basic instrumentation. This thesis will discuss the use of piezoresistive
microcantilever sensors as a transduction mechanism for detection of volatile organic
compounds (VOC's) using MOF coatings. It will be shown that by coating a
microcantilever with MOFs it is possible to detect low levels of different VOC's
(hundreds of parts per million). Excellent sensitivity and a simple transduction
mechanism make these devices low power and highly compact. Such devices would be
capable of detecting a plethora of different analytes at low concentrations. Devices were
engineered for maximum response and microfabricated in the cleanroom with high yield.
A custom setup for testing the devices was designed and machined. A number of MOFs
were selected and tested, their response was recorded and analyzed. Twelve different
analytes including eleven VOC's and water were used to characterize the MOFs.
Microcantilever sensors were shown to be durable, reliable and stable in long term testing
despite being subjected to many different analytes. MOF coatings proved flexible,
durable, stable and reversible. This work will show a promising new technology for a
next generation gas sensor.
Sponsor
Date Issued
2013-07-03
Extent
Resource Type
Text
Resource Subtype
Thesis