Title:
Synthesis and stability: Metal-organic frameworks exposure to water, sulfur dioxide, and hydrogen sulfide

dc.contributor.advisor Walton, Krista S.
dc.contributor.author Hungerford, Julian
dc.contributor.committeeMember Lively, Ryan
dc.contributor.committeeMember Sholl, David S.
dc.contributor.committeeMember Wilkinson, Angus P.
dc.contributor.committeeMember Nair, Sankar
dc.contributor.department Chemical and Biomolecular Engineering
dc.date.accessioned 2020-09-08T12:38:53Z
dc.date.available 2020-09-08T12:38:53Z
dc.date.created 2019-08
dc.date.issued 2019-05-13
dc.date.submitted August 2019
dc.date.updated 2020-09-08T12:38:53Z
dc.description.abstract This dissertation explored the interaction that metal-organic frameworks (MOFs) have with water and acid gases, such as sulfur dioxide and hydrogen sulfide, to develop structure property relationships. MOFs are a class of materials that have shown potential in a variety of applications including separation, catalysis, and storage. However, little is known regarding their interactions with acid gases, specifically SO2 and H2S, which are constituents commonly found in flue gases, sour natural gas, and in other industrial processes. Better understanding of these interactions is an important step in creating MOFs for industrial applications and is the focus of this dissertation. Equilibrium adsorption experiments, flow-through exposure measurements, and breakthrough measurements were collected in order to assess the MOFs adsorption and degradation properties when subject to water, SO2, and H2S. DMOF (DABCO MOF) was selected as a platform material to develop these trends. DMOF was selected as it is highly tailorable through both linker and metal substitutions, making it an ideal candidate material. After exploring the water and acid gas interactions in DMOF, this dissertation further explored UiO-66, ZIF-8, and Cu-BTC.
dc.description.degree Ph.D.
dc.format.mimetype application/pdf
dc.identifier.uri http://hdl.handle.net/1853/63501
dc.language.iso en_US
dc.publisher Georgia Institute of Technology
dc.subject Metal-organic framework
dc.subject Sulfur dioxide
dc.subject Hydrogen sulfide
dc.subject Acid gas
dc.title Synthesis and stability: Metal-organic frameworks exposure to water, sulfur dioxide, and hydrogen sulfide
dc.type Text
dc.type.genre Dissertation
dspace.entity.type Publication
local.contributor.advisor Walton, Krista S.
local.contributor.corporatename School of Chemical and Biomolecular Engineering
local.contributor.corporatename College of Engineering
relation.isAdvisorOfPublication 11d95268-9448-4cff-b662-e0799a34d2a6
relation.isOrgUnitOfPublication 6cfa2dc6-c5bf-4f6b-99a2-57105d8f7a6f
relation.isOrgUnitOfPublication 7c022d60-21d5-497c-b552-95e489a06569
thesis.degree.level Doctoral
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