Title:
High-density capacitor array fabrication on silicon substrates

dc.contributor.advisor Tummala, Rao R.
dc.contributor.author Sethi, Kanika en_US
dc.contributor.committeeMember Gerhardt, Rosario
dc.contributor.committeeMember Raj, Pulugurtha Markondeya
dc.contributor.department Materials Science and Engineering en_US
dc.date.accessioned 2011-03-04T21:02:07Z
dc.date.available 2011-03-04T21:02:07Z
dc.date.issued 2010-11-19 en_US
dc.description.abstract System integration and miniaturization demands are driving integrated thin film capacitor technologies with ultra-high capacitance densities for power supply integrity and efficient power management. The emerging need for voltage conversion and noise-free power supply in bioelectronics and portable consumer products require ultra high-density capacitance of above 100 μF/cm2 with BDV 16-32 V ,independent capacitor array terminals and non-polar dielectrics. The aim of this research,therefore, is to explore a new silicon- compatible thin film nanoelectrode capacitor technology that can meet all these demands. The nanoelectrode capacitor paradigm has two unique advances. The first advance is to achieve ultra-high surface area thin film electrodes by sintering metallic particles directly on a silicon substrate at CMOS- compatible temperatures. The second advance of this study is to conformally- deposit medium permittivity dielectrics over such particulate nanoelectrodes using Atomic Layer Deposition (ALD) process. Thin film copper particle nanoelectrode with open-porous structure was achieved by choosing a suitable phosphate-ester dispersant, solvent and a sacrificial polymer for partial sintering of copper particles to provide a continuous high surface area electrode. Capacitors with conformal ALD alumina as the dielectric and Polyethylene dioxythiophene (PEDT) as the top electrode showed 30X enhancement in capacitance density for a 20-30 micron copper particulate bottom electrode and 150X enhancement of capacitance density for a 75 micron electrode. These samples were tested for their mechanical and electrical properties by using characterization techniques such as SEM, EDS, I-V and C-V plots. A capacitance density of 30 μF/cm2 was demonstrated using this approach. The technology is extensible to much higher capacitance densities with better porosity control, reduction in particle size and higher permittivity dielectrics. en_US
dc.description.degree M.S. en_US
dc.identifier.uri http://hdl.handle.net/1853/37259
dc.publisher Georgia Institute of Technology en_US
dc.subject Capacitors en_US
dc.subject ALD en_US
dc.subject PEDOT en_US
dc.subject Copper en_US
dc.subject Sintering en_US
dc.subject High-density en_US
dc.subject Capacitance en_US
dc.subject.lcsh Capacitors
dc.subject.lcsh Ferroelectric thin films
dc.subject.lcsh Nanostructured materials
dc.title High-density capacitor array fabrication on silicon substrates en_US
dc.type Text
dc.type.genre Thesis
dspace.entity.type Publication
local.contributor.advisor Tummala, Rao R.
local.contributor.corporatename School of Materials Science and Engineering
local.contributor.corporatename College of Engineering
relation.isAdvisorOfPublication fe05ddb2-e957-4584-ac88-58a197df62aa
relation.isOrgUnitOfPublication 21b5a45b-0b8a-4b69-a36b-6556f8426a35
relation.isOrgUnitOfPublication 7c022d60-21d5-497c-b552-95e489a06569
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
sethi_kanika_201012_mast.pdf
Size:
11.91 MB
Format:
Adobe Portable Document Format
Description: