Title:
Chemical reaction dynamics within anisotropic solvents in time-dependent fields

dc.contributor.author Hershkovits, Eli en_US
dc.contributor.author Hernandez, Rigoberto en_US
dc.contributor.corporatename Georgia Institute of Technology. Center for Organic Photonics and Electronics en_US
dc.date.accessioned 2013-04-09T20:08:38Z
dc.date.available 2013-04-09T20:08:38Z
dc.date.issued 2004-12
dc.description © 2004 American Institute of Physics. The electronic version of this article is the complete one and can be found at: http://dx.doi.org/10.1063/1.1829252 en_US
dc.description DOI: 10.1063/1.1829252 en_US
dc.description.abstract The dynamics of low-dimensional Brownian particles coupled to time-dependent driven anisotropic heavy particles (mesogens) in a uniform bath (solvent) have been described through the use of a variant of the stochastic Langevin equation. The rotational motion of the mesogens is assumed to follow the motion of an external driving field in the linear response limit. Reaction dynamics have also been probed using a two-state model for the Brownian particles. Analytical expressions for diffusion and reaction rates have been developed and are found to be in good agreement with numerical calculations. When the external field driving the mesogens is held at constant rotational frequency, the model for reaction dynamics predicts that the applied field frequency can be used to control the product composition en_US
dc.identifier.citation Hershkovits, E and Hernandez, Rigoberto, "Chemical reaction dynamics within anisotropic solvents in time-dependent fields," Journal of Chemical Physics, 122, 1 (January 1 2005) en_US
dc.identifier.doi 10.1063/1.1829252
dc.identifier.issn 0021-9606
dc.identifier.uri http://hdl.handle.net/1853/46698
dc.publisher Georgia Institute of Technology en_US
dc.publisher.original American Institute of Physics en_US
dc.subject Brownian motion en_US
dc.subject Reaction kinetics theory en_US
dc.subject Stochastic processes en_US
dc.subject Molecular reorientation en_US
dc.subject Diffusion en_US
dc.subject Solvent effects en_US
dc.title Chemical reaction dynamics within anisotropic solvents in time-dependent fields en_US
dc.type Text
dc.type.genre Article
dspace.entity.type Publication
local.contributor.corporatename Center for Organic Photonics and Electronics
relation.isOrgUnitOfPublication 43f8dc5f-0678-4f07-b44a-edbf587c338f
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