Research. I saw. OK thanks a lot. It's really a pleasure to be here for two reasons first of all. I mean I'm very well aware of the very nice department in chemical engineering and the research done goes on here in Georgia Tech and second to where I would kind of neighborhood is. Only one hour away by plane. So you know even here in the south even though I'm not from the south. I have learnt something already. And this is that here in the south you like and respect your neighbors. So it's a pleasure for me to be here and tell you about the research that I have performed together with my group at North Carolina State University. I'm going to begin my talk actually by acknowledging the people who have contributed Maston who have actually done the experiments and then end up actually work in the research that I'm discussing here and you said the graduate students we have contributed to the contents of the dog that I'm going to present some of the past. Dogs and some of the faculty in the different types of cooperations that we have on the projects. Of course I would like to acknowledge very much in everybody in my group as you can see we have very nice weather same as you know and also I would like to acknowledge the sources of funding and cooperate if institutions in this project. Usually when people begin their talk dative about what they're going to speak. But I'm going to make a little bit of a difference here because I'm going to thirty first of all time not going to speak about. In terms of you straightening that is serves to do in my group in marginal perspective we do have quite a bit of diversity of projects which relates to the Clearly it's in the after minority and soft matter the way we like to call it is this we're interested in someone else which can be as simple as micro rats firms to do is Asians Hence I find that it serves as has been performed here by Sven very interesting. We're interested in various types of for self organize particles part of material so we do have some work in nano fibers. There is a time going to discuss here is relates to quite the assembly and making new types of devices. When it comes to new types of devices there are some devices that I could not include in my talk which relate to microfluidics another area for research in my group and when we do microfluidics we like to include so we like. Everything that come by and some kind of chemical engineering can Tillich to the city in one way or another. And so we're interested in making come microfluidic devices which can through which contain electronic elements as pumps or do it. Interested in making small particles that are electronic device on their own and that they can move that can move themselves around liquid if you have interest in any of these areas. Please do not hesitate to come and speak with me after afterwards as much as I have time here on what I would like to present to say. I would like to present the. Starry af how we can use again like electrical fields and soft matter in ways that we find to be interesting and that we find inspiring. So the standard that I'm going to presume to sensually reflects what happens when you have a party CO or sassed matter. In liquid in the liquid being too outer and in your prior lexical fields. Generally when you have a particle you are going to have charge of the particles when it is in water this is what gives a particle stable. The charge on the particularly involves the socket countering only Clare. So of course the heard there was a whole complex of particles and I don't surround it is going to be Elektra neutral. But you have a dense lair of highly concentrated IOS next to the particle. If you are political feud that Iowans are going to try to go out to as electro the opposite charge the particle as is trying to do the same. So you are going to have a little bit of a separation between the particle on the counter the only god most here. The separation of the charges around the particle are going to lead to the existence of an in use dipole inside the particle. In use that person or from physics tend to interact with each other and they tend to interact also we diffuse that causes them. We use this type of interaction and this type of motion in our the violence around the part because in order to manipulate and the same bird different types of riders suspensions I'm going to discuss in the first part of my talk. There is something cause that one can do when you have counter ions and this is safe. The counter ions being the source of come back terms we discussed matter within liquids we didn't we didn't rather So in the second part of my talk. I'm going to present a new research area which we have developed in the last couple of years and which we find interesting. Where we take rather basic hydrogen. We drop the hydrogen we probably electrified molecules and we use the high going to jail as a component of an electrical device. The electrical component the electrical conductance here in this case comes again from the counter Yani clear easiest. This near the backbone of the poly electrified. So if you have a pallet right molecule you're going to have counter I don't sit around here this counter islands are going to be misplaced by the future. They're going to conduct electricity in this case in the form of i OS. I'm going to demonstrate how we can use this conductance in order to try to make new types of devices. So I say she need. We are going to master the aware of the time we're going to be presenting the relation the fact of car particles can get polarized and how. Yeah you only conductance based on how you only polarization. Can live through electrical properties that we can harvest inside the water jar. So this is this is the first topics if you have a question along the way please don't hesitate to stop me and ask right because I'm going to cover a range of topics which relate to such type of the effects inside of liquid systems. So I'm going to focus first on the way the assembly based on electrical fields. This is the favorite topic in my group for many years now all we have been doing Karate the assembly all know kind of lens scales. So these are examples of fast track shoes that we have assembled in different studies the departed in the in my group and this is an example of the lens care also which you can do quite a lot Sammis taking part because out of suspension and making useful materials out of them is certainly an interesting topic and it is sort of fascinating because as you can see you have a variety of nice. Well organized structure is so interested in organizing well. Well. Structured ideas of particles. We're interested in using such R.A.C. and for new types of pot of materials. I'm going to discuss how we can self assemble particles in electrically conductive structures we can make up soon as. Special types of porous particles and other assemblies that our some of which I'm going to mention in my talk. Greg are saying we can be accomplished on the. Scales starting from now on the meter sized particles of two millimeter size photonic crystals. It is not hard to assemble particles. If you just take suspension let you drive on the Nano said if he's going to the surface am going to some think the mass famous example being the case of up what happens if you happen to spill your coffee. That the Patrick arse out of the coffee are going to self assemble into the sack called coffee drink. That has been fascinating for journalists because now they know why coffee makes stance which is important in the journalist profession right. How are you going to skeptical ingeniously wrong to achieve assembly that can be kind of astute regards to making practical structures. Cance our interest in electrical fields comes for the ability to tune the parameters of the process and make it rapidly. So we can achieve the same being the way that we design and we can do right I'm going to mention later on that a kit and program to assembly. This is a novel view of the different types of processes that can be used in quite the assembly. You can have something as simple as sedimentation which means particles go to the bottom of the vessel on form a structure. You can drive the particles have a surface of the like I just mentioned coffee think is one of the structures but there are bad more useful structures the Other than that you can assemble assemble them entirely later why not their lives were like some of the research that goes on here in the Georgia Tech including Professor chocolate for example. You can assemble them around droplets which is another topic of interest. I'm going to be discussing color what happens when you have particles inside electrical field we part forces and to make them come into some kind of useful structure. Before I begin that I would like to discuss the forces that are that exist inside suspend. When a party goes in a rotter between electoral votes. Then I think you're seeing there and the illustration that I showed on the second flight. I had class and minus. That I could confuse the two million that to use in my group are typically after an eighteen. There is never pass and minus a saga because I mean like the direction of the few changes all the time which is of the frequency. However we still have parity ization of the counter you only got most fear under one condition and that condition would be. Well the condition would be that the frequency should be low enough because science cannot move too fast. So if your frequency is somewhere within like I mean less than let's say ten to one hundred strange but I don't scan will distribute themselves fast enough. TURPIN just parrot ization in the particle and the Paradise party course are going to like me have a dipole which is going to interact belt with the fuel tank in between the particles they internationally the of the paralyzed particles with the fuel that induces the polarization is carbolic to four is this as a pastor electrophoresis which is in constant field. This interaction typically leads to either attraction or the power of the particles around the direction of the fuel gradient particles which are more paralyze a ball than the medium which is the typical case that we study are going to be attracted to as they have high fuel gradient. That means that they're going to go today of high field intensity as shown in this image. But if the particles are also the diapers inside the particles are also going to interact with each other. And this type of interaction is going to pick a lead to the formation of structures which are well known for electoral logic on Magneto article fluids which were the particles from chance. That would your fusing collected go fuses that we can turn the field on the Dante moment we can control the frequency we can. Control the parameters of the fuel. So we can use it up it assembling by just tuning the parameters kind of turning the knobs on the equipment we went to understand how the process. GROSS So in some of the slides I'm going to have the results of a link to the study simulations of the energy of the fuel intensity and then adjust interactions such as the one shown here. This is a software simulation of the fewer the intensity. In the system that is shown here to electrodes on the surface of your particles what you can see is that because of the higher power is ability. You have higher fuel intensity around the power of the curse. This is essentially the result of that poor poor is asian of course who are cowards here did not hire a field intensity that every lap of the disturbed feelings between the part of us is essentially similar to the diaper our interactions that is that is showing here. The few would you have the few without a lot is going to lead to attraction of the particle you can see that this is being asked of kind of direct of what is because the particles would like to get to the area of high viewing density. So the class or they get the higher the field and dance in between until they come together by doing similar type of simulations. We can we can calculate the energy of the interactions of the particles and I'm going to present somebody like that a little bit by that all. You know to understand such type of systems we should also consider what happens when we have two types of particle similar to what we study metabolic and the electric particles. Obviously metal as you know it's very highly patronize a bow to the extent that it even conducts electricity. It's a very highly polarized environment you know metallic particles inside electric fields are going to disturb the fuel very much. And there is going to be very strong forces induced on the particles dielectric particularly as are paralyzed but to a smaller extent. So they're still going to. Be attraction between thought there is a particular reason there is still going to be attraction to the electrodes but not to the extent of stronger so if the metallic particles drop out ization of the metallic particles comes mostly because of the polarization of the electron qual to the metal the pair ization of the delicate particles count because of what right is the start of my talk right it cuts. OK it counts because of the poor is ation of the counter you only got most ferrite by using this through a parameter so you can control the interaction of this I'm going to illustrate a little bit. I'm going to present First of all some of our earlier research. Interactions field interesting deductions between metallic particles and dielectric particles and then discuss how we can use them in Mark complex type of assembly. Sometimes the particles came be too small to interact with pass on their own. However if there metallic particles you have strong forward ization strong forces that direct you for resisting the attraction of the particles to add the fuel gradients can still you make the particles come together and sell his hammer. So some time ago we found out that one can take some system which is a simple fast metallic nano particles. I'm sure that some of you are working in one way or another got on the particles and. It's a very simple system we use to make it part because they're not statically protected. We apply electrical if you would have happened says the particles get attracted to ours electrodes. The growth on the particle or sorry you weakly stagger right. So if you concentrate them too high. They're going to be begin again when the aggregate they're going to do something which was also shown on the previous life which means that they're going to extend their elected all the little bits for the round into the suspension. So the end of their throat is not a. Going to be here in the regional. Area through all the end of the of the of the metro is going to be at the end of the micro why that is partly why and that is made by the assembly of this particular snarl. Has a very high purpose. Have high electric field intensity at its end. So this is still going to drive not a metallic down the particle. They're going to come out very good at the end of the ride. So we're going to have a spontaneously growing system which you call micro I add in these unused ration of the process in a static snapshot. You can see the structure from metallic now on the part because that had been collecting and that is collected and that is collected the power to collect in the new particles here. This is actually a movie of the process. This is a little bit speed it up but you can really have a really really observe the process. On the microscope and see how the the nano particles get sucked Howard collected by the growing and the while you can also see some fractal type of growth. It is not continuous fractal because you can see that there are branches would stop growing. After a while but you have the formation of a continuous structure that I'm sure I can me has run just around it has this structure grabs it kind of you can see it through how it vacuums how then on the particles in front of it. It is going to continue and you're growing and you with it is that electrodes and now we charge circuit the system there is strong current going to go into a wire. So we can think of this is kind of a self assembling electrical circuit out of nano particles because of the electrical field. We can measure the process US illustrated here by calculating the fuel intensity finding out where the party goes are going to get collected adding the particles to that area. Recalculating the fuel to continue this process in the manner. As you can see we can capture the most important dynamics of the process which is the from a. Branches would stop growing. So we believe that we understand pretty well the type of process that occurs we can assemble the metallic structures relatively easy. The take home message here is metallic particles strong interaction in the field and strong strong for his age we can do a similar experience monthly to chant but where we take directly particle. Counter you only got mostly a poor relation only the interaction is not a strong but still enough to collect the particles of the sample they mean to a new type of structure. The experiment here is performed in the team chamber. Two electrodes on the side you can see the particles even though not very clearly because they're in Brownian motion this is going to be a movie. So you're going to see them a little bit better in the second we apply electrical fields and the particularly in this case large particles which is not going to get by just get together are going to fathom of course chance. So here is what happens here is how it looks. This is the real time movie The particles are large enough so we can observe them with a microscope these are modest tides of years the party started spheres come together and form my Hex I win the lottery retard not the fuel the Brownian motion this is Sambo's them. This part is the back. We turn the fuel down again we have the formation of a structure again. So this type of structure in use if you do structure formation in the suspension can be repeated many times if we choose the right types of conditions we can actually have a very good diffraction laser beam through the system the very same way in which one can study. Diffraction effect straight through a molecular Crystal we can study the formation of the structure by diffraction broke right or crystal. This is an example of the type of structure that are you the type of diffraction pattern that you can observe when the structure of the crystals is good you can see that this is a. Three clean six pegs that are what you straights almost perfect crystal this one is not an almost perfect crystal. But you can make it better by choosing the right conditions. The formation of this type of crystal is again something that is interest of many people related to photonic materials and again this is a repeat of all process that can be for a time. So now we know what had happened to the directory particle. We know what happens in metallic particle. We want something that's a little bit more complex or comprehensive with regards to structures. I'm going to give a few illustrations of the work that they have performed in. Making structures out of more complex pattern. It's something that they are included in my presentation having in mind a very strong biological on biomedical research performed here at the Georgia Tech is. Interaction between lie a lifesaver also sparred because of a kind of dilated experience where you want to use the leg to go future normally in order to call Sambro are several particle structure by Com been a by drawing the SAS and the particles together in by the field. The first movie shows a simulation of the process where we have to live so as in this case we just use the parameters of the cells of the dielectric particles of our kind into small particles you're going to observe that when you let them move this map out because get attracted to the area of Haifa the density next to the sail gathers here are also gets attracted this bad because they actually paired the bigger sideways. But this particular got trapped in between the life cells. Obviously this is a process which came to use for a sample of new types of potentially biological Lee inspired structures a kind of combining these by a composite material use cialis in our case because this is an example of a movie of an actual process. That it's a little bit fuzzy because this is very high magnification you can see you see us here on Late expired because when you turn on the fuel you can observe the process that goes illustrated in the simulations where some particles are trapped in between the Sallisaw that are trapped at the end of the chain but the math on line is that you can have alternating chains of live cells and particles assembled on the action of the electrical field. We can use a similar person or to make my curiosity was traded on the next slide. Here you know being a chemical engineers who always like to say that the model predicts the behavior of the system actually we have done this in parallel but who had a lot of pain such a good correlation and they believe understand the song. Now we can use this process you know to take use SAS. Take particles that have like him. Call called on the really a that is a protein that bias to the chains on the cell surface we can find on the few or the part because on the say our scan assemble into a chain like structures that are going to be irreversibly assembled. If we use magnetic particles then we can have moderate EEG by a composite assemblies we can use them magnetic field in order to manipulate this that called the form particle cell Y.R.'s we can apply a few wood in two different directions. Or do it in the same bow cell particle membranes a stripe of new bomb material. So this is one example of how how one can use this on cheap in order to make new type of structures. Potentially such materials can be used for microsurgery can be used for other types of census from our perspective it's important to understand the fundamentals of the process. Speaking about the fundamentals of the process I mentioned that we would like to go to Mark complex systems so dire our present interests are related to particles that combine both the. There's a math on that I like the name for certain type of particular see if they're half metallic and how the electric is Janus part because that comes from the from the Roman grabbed out supposedly had two faces. So you can have a two phase particle phase being met. I want phase being that like three or that you have a patch of particle where you only have a small patch of Maddow on the side of the particle or maybe Madama patch this type of pad because of an example of course people you saw not and in color. It's an interest in these days right Hugh Grant from systems that had been studied for more for many years to systems of higher complex if you were to have some kind of organ structuring pattern you got out of initiation will NOT a particular level. So now what happens if you are pulled this type of particle it obviously has two properties. What happens if we take such type of particle and put it in the electrical field. Yes it is many things can't tell but first of all I'm usually getting a question of how do you get those particles. So I'm I just want to very briefly mention how we make. And whether they really made up. We have news of the prize it being fairly steady microspheres or in type of particle in the lead by using a devise developed in my group we can. Up the President Arafat because we can put them in a matter of OPERATOR You just part because of polymer spheres of silica spheres the matter is going to be deposed you told me on the top of the sphere. We disperse them afterwards. We observe first happened so this is an example of the type of particles that we have you can see here and. Dielectric is the darker part of the matter is the brighter part in the C.M. so we can have metal. Particles. I collaborate any of our boys you want to create murder from the University of New. Casper just made up for that. So she not only that passes them on the legs but she can hear them the present matter on the particle. When you deposit metal at an angle you're going to have less than half of the particle being carted you can turn it around you can deposit a patch on the other side. So you can make batch of particles we take those particular US for them in an electrical fields and lots of phenomena can be observed. It's really a very real property is and this is just an example properties of Venus particles because it's a new area to search some of you may be working in see more areas related to other properties of this particle such as interesting as option the surface problem is the first phenomenon that I ran discuss in detail here is what happens when the frequency is below that our tank your hands where I mention the counter atmosphere can get Parise Well now we have a particle where the county only God knows me and moves around you have strong correlation in the metal less strong correlation the dielectric you die on Scared respond to the fuel the particle can move around by an effect which is called AC electro hotter than nomics caused by the gradient of the fuel round the particle itself. What you what you saw in the movie here is that the particular smurf in the very specific where you had the fuel in this direction they are moving perpendicular to the fuel. We have a dielectric side oriented Ferarri the reason is again the gradient of the fuel on the surface of the particle and the musician the particles if you are not going to describe this too much. If you're interested please let me know out there in MA that this effect and I'm going to discuss the more simple case of what happens when the particle or side of the higher fuel into at Highfield frequency. When you are having different power ization within the metallic power. In the direct path. Again I only can count on the one you got most years paradise for ice less than the metal part. So now you are going to have particularly strong however which is more polarized lets you put them in the electrical field. You see chains but these are not the chains that we have is that when we had the electric particles you would take a look here you see that this is a kind of staggered chains where the metal actually is the one that has assembled into a continuous structure and the ballot for the car set a facing sideways so round. We call those we staggered. Obviously this is a new type of structure which is standard because we have difference between the two hops of the part. You know to understand the formation of such type of. We can start a family that is called quasi Monte Carlo simulations which means that we have a complex potential of interactions. We can not perform a regular Monte Carlo simulation but we can calculate then your use of a few different systems of selective configurations and compare them with experimental results you take a sphere organized. So it is it's a crater is facing the director in the direction of the field. This is the experimental legs of that action we can normalize that energy without. Even restart turning the spheres we're going to calculate different types of Asian energy as a function of the orientation angle the highest energy that is the least favorable going to Gratian is the wrong when the particle last are facing ninety degrees with regards to the most preferred if we start rotating this field as we are trying to find our. Standard use when the particle sorry ass. We have all the metal sideways the other car bell. The other side by the few that actually use around the equator of the party. So we understand why they have a sandbag why they have carried themselves in this way. We can not take the same bodyguards and now report for the particles in the simulation racks we start playing when they're out of a new station in order to find out whether the experimentally observed configuration is the minimal energy or one when you do that you find out that first of all we can say why am I mean that if we just make them like a sample into a chain the very same way that you see the regular sphere Saudi. Each with a God I mean we get to have pretty high energy even if we put the Michael the gold on the opposite side if we turn to God to be facing one side and if you can easily do a bit but it's true is not the slitter of the energy in the experimentally observed configuration. You can they say right if we have a staggered change maybe if we change then go even further then misplace the particles even further. Good. The simulation is going to give us large energy but if we just change the angle than the experimental observed wrongly see again you jump in. Then. So if we keep I can summarize here the results we can say the following The metallic thought ization is the one which drives assembly and the experimentally observed that we calculate by finding out this type of system so we believe that we know about gross song so we can make more complex types of assemblies than even the other shown here. Even the structure that they show old can can be used in a variety of making new types of horrible structures such as the Met our dialectic Christo shown here. So you see again idea of particles assembled on the few words. However these are Janus particle us. So we just not only that you have violated sphere organization but you have heard in these Asian of the metallic parts of the spheres and these metallic spots in this case if organized themselves in continuous chains around the crystal So we have not met our the electric Loftis. Under the direction of the electrical field. So start of my two years can be used in different types of fun as a tropical conductive or a tropical thermal country many conductive structures for a variety of new types of mine. Here we can make even more complex structures you take patch of particle and so this is an example of what happens you would take a particularly just more patch on the campus and God called it. Your god to high frequency where the dielectric or ization. Is very much suppressed. You know the future and you have the formation of structures like this part of this seems to be Understand that way because particles strong chance by path because from changing the direction of the fueled Why would part because from chains perpendicular to the field. I'm going to give first the explanation the kind of the simple physical explanation of the process and then I'm going to support it to a day we believe that this is the first time where one can and that it will have a path to grab the power interactions between the particles we have to use that the Iranian the metal being. A Darker of higher polarization than the few would gather around in there like you have polarization so the two drivers are facing in opposite directions when you have bad repairs that is too bad that are stating in opposite direction. You have two types of assembly belt of which are favorable interactions between two cars recalled they can organize themselves in a chain or. Perpendicular to the fjords or they can organize in a chain in the direction of the field. So we have part because. Rich fat. Two they mention those structures the interesting to hear from the perspective of let's see if being a process education. You have farming Jale which is cross-linking to their actions by a prying if you're the only one that action. The jar can be the thing for a variety of publications and it can have better properties than the jobs that are found by simple part because interacting by that or poor ization all we have begun to surpass the hypotheses for quadripolar interaction. If we perhaps again in this case dangle forth ation of the power of the cursor around each other. And then you would find that we descend the energy has to mean interactions which are exactly the position of the Quadro forcing to interchange it with that action. So Sam. Let me summarize while they have softened. We have particles which are going to change in the direction of the few articles which are going to assist I got a chance for articles which are going to Nice in that action on purpose because of the few it. But then you can see the rabbit attacking you are going to hide them in some other that action not a problem with a crowd because we took patches. So now they exist as of two patches leads to the formation of this structure where as you can see you have chains. But but this chain set a degree of forty five degree with regards to that action in the field. So we can organize them. But actions which do not even correspond to the field that action. I'm not going to present to my need to ask here but the reason for this type of assembly is that we have a hexapod interactions between the type of particles which lead to this type of particles which lead to the assembly in change in different directions. So if I may summarize this first part of my top. We believe that we are on the earth from regular coreutils sand lead to that act of assembly at the present stage and moving called to work to call program to send. Meaning that we design particles that specific properties and specific patterning we put them in the inside electrical or maybe magnetic fields on to assemble or structure by design. So hopefully this is going to be another indicator that action that is interesting. Whatever I do hope we cations such materials can be applied in many new types of systems but of course from our perspective this is more of a fundamental understanding of interactions caused by counter yawning and metallic or ization you feel driven system. In the remaining part of my talk I would like to focus on what happens. OK So this is how we can assemble particles can you do something careless when they have fewer than core I though systems. In this case in water based suspension. So I mentioned in general I will. Very briefly your straight how we can use now the only conductance of generals in order to try to make new types of devices. So we would like to think of a jackass a new type of electronic my Furio the jazz that to use that very simple we take I got ass. I'm sure that many of you are familiar with this type of system. Master of it is of course a lot of. Up to ninety nine percent of the Jerry's math on there is to buy a poly mother which is why I mean very inexpensive as these don't think we're interested is this type of systems because we actually have quite a bit of inspiration of how one can use jazz for new types of structures that are for most of them functional. The mast important from our perspective structure around impact the structure shown here which is good in lives. But the most important structure from our perspective is actually ourselves because Live matter is in one way or another similar to jale water based outside. And obviously we're actually operating as electronic devices because our brains. Tends to operate on the five electrical circuits which are best to solve math. So let me illustrate how we can use just new types of soft math and even devices but for simple devices that one can make mistake two types of jets then have them with parallel Lector rides or different charge ramp as if you charge one negative a charge. We are going to have to you only conductance from the counter IOS but there are two types of counter I also which can either go to as they like Rad so we can go and they got a lot of the drives and Mido in one case are going to have current in the other ones we're going to going to have to run this is very similar to the operation of semiconductor diodes or lead the charge carrier here is different the charge carrying Jr in Jabe's devices are the IOS the charts carious and semi semiconductors is of course. Was. The formation system devices very simple. So my graduate students pretty much by a little bit of us on the stall like not in the store but on the lab bench and proper them in like a mean simple encourages and you have a water based device. This is an example have performance of such a gel based device. This is the poor out of the current as a function of the voltage where you have a pretty high current if we got through this fall in this case. Conducting their action there is almost no current if we grab a valve. We can make similar devices by using just one type of the gel off our kind that lead to hydrated silica layer on top of silly silly Conway furnace. So we can take a silicone way further we can just interfaces with a gel. The silly car layered on top of the silly Kong is hydrate if you to last only hydrogen. I O's that is proud to go through. So now we have two types of gel like my Cheerio Ronnie said if you show Jad there either one is snuggle scared. The interfacing of these two types of jazz used to the formation of very strongly rectifying. Junctions. You have poorly tried and if we choose the right conditions we can have the so-called rectification ratio which is the ratio of the current in the leg in in the conducting that action divided by the current in that it was that action. Being as high as forty thousand. This is good even for semiconductor devices. So obviously sometimes with jelly like devices. One can make something that at least in some aspects is comparable to center. And that it may not be as good but it may have other interesting applications and the first impact and from our perspective obligations you Skylon can use such type of gel like devices. You know the to make for the world Tayac cells that is probably type of solar cells the job that I just mentioned conduct electricity because if I own the conductance even we take on a similar type of jazz and if we do use jazz. We have to sensitive molecules which are growing dry or nice on the direction of light. We can't have a scene where the job a device which is going to produce electricity based on human nation of life and that you only conductance through the jar Laris. Interfacing in this case a couple of electrodes one of which is if you all. That is for an eighty thousand oxide Gratz. And would use optical transparent of the platinum medical. We take we make a device like that measured the voltage and the current as a function of human nation. Obviously there isn't much current when we don't have in. Nation rounds to human aid. You can see here the I.V. curve of such a device. The intersection in this case with the X. axis. Gives birth each that can be generated that are not one circuit and the current here gives you the kind of the short circuit current both of those are important parameters another important parameter is the fuel factor which tends to be pretty brutal even though the device itself does not produce that much electricity the current density is comparable to semiconductor. Very modest not semiconductor regular semiconductor devices semiconductor polymer devices have about the same density. This is much lower than usual for toward the cells that you have but still we believe that is an important concept that we would like to develop for. And one of the disadvantages of such type of device. Would be that we have one platen the medic drags you does not make sense to make an expensive Jabe's devised if one of the electrodes is platinum I'm going to discuss how we address this issue a little bit further all but first of all I would like to again emphasize the difference between router based jar devices and semiconductor or even the Markham and VI sensitize ourselves devices where we have done like electronic injection similar today but the devices that are typically used today begin producing electricity immediately upon them. A few lumination Jabe's devises Lagaan that I showed here based on count are the only conductance begin producing begin producing less current in the beginning and the current slowly increase all the time the reason is the dumb ability of the carriers that is diodes in this case is smaller. So we had we need some additional time for violence to reach that extract and produce the current So we really have a different mechanism. Producing electricity down the common semiconductor type of devices are the cells which are a topic of investigation that maybe the searchers. You just consider the general diagram of operation of such a device. We have the two electrodes the gap between them. One of the dice which we infused in the jazz through B.P.. Has a direct feel like you can hear that into the crowd gathered I can hear that recollect running injection into the electron or it can inject dye into the excited state of the repeat. So we have seen you just take action of the two dice in the horse circuit just completed by Diane the current originating from the other side. The combination between Jack thought to excite the bad guys and kind of like a couple of electrons can be a simple way of making a whole new type of belief. For electrical type of devices. For the cell. I mentioned this type of cell wouldn't make any sense if you splatting the muscle on electrodes you can as well make it as out of whack. So we have some ways of her removing the plot in them. It is not a C.Z. because you have to jazz electrochemical potential that electron. However this can be achieved by using a copper electron. Hurted to it. Graphite or any other form of carbon. So now we can make glass very simple devices. Pretty inexpensive the performance of the cardboard electrode line is not as good as that propping them on but still pretty decent for this type of device. So this is what it looks like. Again. Some of you may have heard it or may have read it. We talk again and for the world devices. This is another type of organic for the what I knew to have a fault or get involved will die device. The difference in terms of May. Doris's when you have let's say conducting polymers it's a very complex process you have to have polymers of high purity you're working oxygen less environment or you don't get much out of the device. I mean you ttyrec Christ like. I mean the tremendous effort in this case are there for that my students do us a major he's pretty much by a dagger also on the. On the benchtop and make the device in a very simple way. Even considering devices which mean me can nature we should consider of course how we can use natural that I've thought too sensitive molecules we hear for pain from our core our cooperate is that therefore this is to a bar Very. Biological a biological molecule quite a fuel for the system we have demonstrated that this type of object sizable molecules also generate a current in the devices that. I have been damaged. So obviously we can make new types of. Diet so we can make the advertiser X. If we just try to think a little bit more in kind of vision for the future. What are the types of South organic sort of can't drag based on water based device can make. Well I mean. That or ROSS You saw surrogates. We're using of costs of course salad circuits that is the computer by circuit wouldn't matter much if we did not have the soft sort of kit which operates from rather a beige gel and as it happens there is cried the big interest is this in devices which are called memory serves the usual way of making dollars is by using semiconductors where you can care for Barrett like junction which can memorize the last state. I feel like trickle current that has been passed through the device dangerous in this kind of device is obviously like you see by deflected in the name. If you have an audience this type of devices. You can store information potentially on a very small scale. There is quite a bit of research going on and memorise this by using semiconductor it's kind of various and work. Many people are pointing. Relevance to memorise that type of device used to biological. Biological circuits and memory in terms of the way memory is being stored in the brain. So it would be very interesting if we were there we can make a soft light sort of kid not with memorize it estates you go to the way I mean minister would memorize the direction of the current weather has been high or low. And two would be interested to making such a device out of only some of the liquid matter right. If we would like to make a device like that we should to move you on the solid metal out of it. So here is how we do that. Down. We have one of our faculty. Chemical Engineering at the N.C. State is working with you know called Liquid Metal. This is a new technique mixture. Golly I'm. It is liquid that room temperature. So you have a conductive liquid conductive metal at room temperature and we can take that liquid metal into can interface into the hydrogen diodes seem rode around that I discussed a little bit earlier. But not all the properties of the liquid metal that bent on the properties of the JR that they're interface you're have Jass a deal with different parallel electrolytes responding with given the age the liquid metal is going to further my skin or not far Musk in depending on the action of the current and the parallax arrived at the interface is the matter. So now we can have this device which here selector outside of liquids in their face. Ian Gray. We can begin investigating and that is dependent on to demonstrate that we have two states of conduct answer such a device if we apply. In the beginning which operates the high current We are going to Fred among oxide skiing on one of the gods so one of the electrons can kind of memorized the other one being used now we flare current in the opposite direction we're going to read the State of the rather see if we have written about a few information in the device. So if we reach here the voltage of zero. We we can go back to discourage going to operate on the device which has sky high and assistance. However if we grant a negative current They're going to raise the by that information. So now if we go back again second time to do this type of curve. We are going to have a second. Studying of A By that he formation inside the device so we have a bed by stable device and that is distance of this devise the pans in the prehistory of the current. So now we can play it out of course if we are making a device like that we would like to demonstrate that we can make an IRA which starts at least a few bytes of information so we can make this. Electron. Crossing collect all of the crossbar electrode device with. Memory based in ministers' between the electrodes and where they have done it so that we have what they have demonstrated is that you can store a bytes of information inside each of those independently. This is an example of how we take the. We change the state of one of the. Returning to the original stay. Take the same notes and turn it back to the original state take another no and start to buy that information return it back so we can really do this and the higher the rise. You see shown here it is essentially again the same nation. There is nothing solid I mean it is. Just crappy game is basing gradually to liquid metal electrodes. Rather hydrogen patches inside. You can bend it straight and Sarai did based on that you can put it in after it is still going to operate. So we believe that at least in this type of device. We can if you are straight in the power of what we can do when a soft matter either gels and used a counter IANA conductance if I would like to illustrate. Right. If you are excited about this research. This is it. So first of all the world like to make new types of for the world devices operating on hydrogen No because you would like to meet the properties of nature of art of all types that this liveliness if you can see the leaves and you have some kind of hydrogen. You may notice that our devices to me miss one of the important features of Wired lives which is carrying the so-called vascular network of cargo it is providing water for its form or maintaining its function. We are presently working on new types of devices where we can actually provide additional nutrition and not nutrition but in this case why condition no surprise. The four target market kill biomolecules by using. Michael channels and doesn't mention microfluidics is one area where they acquired the edge in my group the site itself it's really a forum for a mom perspective our inspiration. After our one day maybe we can think of interfacing the subcircuits with the. The solid circles that are made to artificially there is quite a bit of the. Interfacing it's a brain or life issue with electrical circuits we believe that we have the means of achieving that in the future. Right now it's more of a fundamental research of understanding how our young conductance can be used in such to happen. Lies. So let me finish with the big vision here and just. Go back to the topic of the hard work and try to summarize different points that I hear your state of mind. So I have a value on a few straighted that. We can use the counter you only conductance barracked in the case of particles and in the case of hydrogen those for the same with new types of structures for the fabrication and new types of water based devices. I did not discuss that model but the mobility of this science can be used. Also in new types of self-propelling particles or microwaving devices. But in general we hope. That at least you can get a taste of. How D.C. area can be used to new types of materials. Maybe new pattern of devices and most important of all we had lots of fun in doing this research. There is a variety of things that they can do or that they can explain and in that period and so hopefully this has given you a taste of the type of the research that in my group. I would like to thank you all for your attention then top course I'll be glad to Ronsard question as much as time permits. Thank you. Who. The way to fix the way to fix the defects here is to make good Janus particles so that the present problem all with the defects here is that some ingenious particles can not come out as good. There is and use that in order to make a very good. Jenna's particles that have accompanied otherwise the metal will deposit also on the sides. The formation of join this particular suspend the star that people are sure. Is one hundred thirty eight research and there are not that many good methods for making Jenna's particles in our research you make just enough so you so we can understand the interactions and they can demonstrate database but making this party goes retired defects is the way to go if you want to make a tonic materials you make to make other types of materials we are not there yet. We tried to stay away from power because in this issue and to understand the physics. But I'm sure there are going to be lots of new developments in that area and hopefully we deserve our months one can make a better idea now of course in this case when you use an echo a few words and meaning of the structure is something that we can always do by turning the field on and off. Unfortunately we can all the new the bad particles are out so we have to start with the perfect suspension of particles and then we can have a very good mentor the electric wrist. Once again would make our the crystals then you have to mean optical forth on the electronic and a variety of other occasions. But you can offer a way to make good Jenna's particles like this. Now that would be great right. This is very hard area of research not in my group but many people are trying to. That's a very good question. And now the bigger genius particles are a little bit less important because usually they would say demand too quickly. So we want to have particles which have swears in imitation of Brownian motion. And this is the size that we can still work and we can see them now. Problem with using small or Janus particles or patch of particles is first of all we have to turn of the fuel because now the energy of interaction is small and second where from the perspective of understanding of the forces us to be more complex because no I mean we can not see where the patches. So this is a bar of the sky optical resolution you can see you see because this by dispatch is so small cannot even see them. So it is very hard to resolve without interruption of the particles in a smaller scale. On we do not care for reasons to expect that small particles are not going to behave in a seam or a man and so the answer in the stand simply a larger part because we believe that then mind Koran's people learn to synthesize them where on a smaller scale one can you see more methods on the same bus structure by design. We are not there yet but through laughter the heart. Yeah. It's a very interesting question. You can let your imagination around the rod of the type of structure that you can get and when you do they experience you actually usually find some surprises. This is what I want you to illustrate actually my talk is that this is a field which is very rich in effects. You have a variety of particles you have a right if interactions and you can form form a variety of structures. So so for that is that is part of the fun that they having this is used you decided to in effect that you would take me as a small or large part because he would take part because the different patches may be complimentary patches Sorry can't have the formation of half particle pairs first and then these particles doublets. Going to larger structures there is a humongous variety of structures many people are doing some simulations including some project where I mean vastly in cooperation Professor Carol Hall from our department. So we even say we can not do the experiment yet so let's predict what kind of structure you're getting but it is a very rich field so that's what makes it interesting from our perspective. Actually we can see Cairo diffraction bought. The higher than the fraction in the media as a short I don't want to go to sleep doctor all to all flights but. The heart of the fraction is going to be at the higher end girl so it kind of quiet I mean gets outside of the fuel the view of the of the this case. So we see Carla diffraction and you just record about we can see. And again these different action pattern you have a part of it is some years ago. But this action by the news part of it with regards to the first or wherever is Canyon the crystal and second to her every time you turn the few you have exactly the same diffraction pattern. So if you said very clean diffraction pattern which illustrates that on a microscopic scale. We haven't yet perfect assembly and this is something that is very hard to achieve in crowd. But we do have a higher order pattern is just not seen in that image actually it's a movie which I did not run. Fairly narrow actually C.C.T.V. because of course by taking the diffraction pattern and processing the data you can obtain the particle that the distance between the particles in the area that is the space. We have shown in the paper that actually by measuring the day by measuring by but I mean this of the diffraction pattern we can measure the spacing between the particles in the IRA through our precision our R.R.C. even to capture the fact of the counter yawning interactions that is there if you start to get a partial So when they are when they had electrodes you can measure the distance between the particles that has been in use by the rector wide by the diffraction pattern so it's pretty precise.